Catalytic decomposition of p-cymene by activated clay.

Tetra­ethyl­ammonium trichlorido(η6-p-cymene)ruthenate(II)

In the title salt, [(C(2)H(5))(4)N][RuCl(3)(C(10)H(14))], the Ru(II) atom shows an octa-hedral coordination in which the aromatic ring of the p-cymene mol-ecule occupies three coordination positions.

Dichlorido(η6-p-cymene)(eth­oxy­diphenyl­phosphane)ruthenium(II)

The title compound, [RuCl2(C10H14)(C14H15OP)], is an Ru(II) complex in which an η(6)-p-cymene ligand, two chloride anions and the P atom of an ethoxydiphenylphosphane ligand form a piano-stool coordination environment about the central Ru(II) atom.

CO x Free Hydrogen Production by Catalytic Decomposition of Methane Over Porous Ni/Al2O3 Catalysts

Unusual dimer formation of cyclometalated ruthenium NHC p-cymene complexes.

We present the synthesis and structural characterization of novel ruthenium complexes containing C^C* cyclometalated N-heterocyclic carbene ligands, η(6)-arene (p-cymene) ligands and one bridging chlorine ion. Complexes of the general formula [Ru(p-cymene)(C^C*)Cl] were prepared via a one-pot synthesis using in situ transmetalation from the correspondent silver NHC complexes. These complexes re...

Encapsulation process of p-Cymene into -Cyclodextrin: A Theoretical Study

A theoretical study using semi-empirical (PM3) and DFT calculations (B97D) was performed in both gas and aqueous phases, in order to obtain structural and energetic properties for the encapsulation process of p-Cymene into -cyclodextrin. Two modes of inclusion were assumed for the [p-Cym...-CD] host-guest complex: (i) Mode A, when the guest is placed in the hydrophobic cavity of the CD by the...